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Organic synthesis has been dominated by chemical reactions that are based on 2e processes, either stoichiometrically or in catalytic fashion.While le radical chemistry is equally rich, its application in organic synthesis has been hampered by several enduring challenges.Over the past decade, we have been in the process of formulating metalloradical catalysis (MRC) as a powerful new concept for controlling both reactivity and stereoselectivity of radical reactions as well as for catalytic generation of carbon-and nitrogen-based radicals from common organic precursors.