THE SYNTHESIS AND OPTICAL PROPERTIES OF LADDER POLYSILSESQUIOXANE WITH PYRENE SIDE GROUPS

来源 :The 11th International Symposium on Polymer Physics(PP2014)( | 被引量 : 0次 | 上传用户:jjjjjjj7
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  Blue organic light-emitting devices (OLEDs) have gained large attention for their potential applications in full-color flat panel displays and solid-state lighting.Herein,a newly blue fluorescent ladder polysilsesquioxane with pyrene side groups was designed and synthesized successfully.The monomer 1,1,3,3-tetraethoxy-1,3-bis(2-(pyren-1-yl)vinyl)disiloxane(PySi-OEt)prepared by Mizoroki–Heck reaction displays special aggregation-induced enhanced emission.Ladder siloxane structures are expected to avoid aggregating of pyrene and improving its physical properties,such as film-forming ability and thermal stability.
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