The influence of zinc on the properties of Portland cement

来源 :The 14th International Congress on the Chemistry of Cement ( | 被引量 : 0次 | 上传用户:z4360877
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  Zinc as a strong retarder of Portland cement was recognized by Lieber already in 1967 and he presented his results during Tokyo Congress.In the mean-time zinc content in cement clinker was significantly increased due to the use of alternative fuels and iron corrective waste materials.It was the reason that in Institute of Ceramic and Building Materials several clinkers in rotary kiln in Pilot Plant were produced, with different zinc content.The examination of these clinkers has shown that in the clinker zincate-aluminate calcium phase is formed which caused the acceleration of cement set.It was due to the formation of aluminate ions from zinc phase hydration, which reacting with sulphate ions from cement, were transformed into ettringite.Only higher content of ZnO in clinker than 1.5% caused drastic retardation of cement setting time, because, apart of zincate phase,ZnO remained in clinker, thus influencing according to Liebers or Arliguies hypothesis.
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