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The simple synthesis of nanostructures with high charge-carrier transport is an important aim for the applications in supercapacitors [1-5].Here,we report a novel hybrid electrode material with mesoporous silica nanoparticles as core and pure graphene oxide as shell doped with conducting polymer nanofibers for supercapacitor applications.These nanostructured composites are synthesized by in situ polymerization of aniline in the presence of mesoporous silica nanoparticles wrapped graphene oxide.