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In the past decades, microporous metal-organic frameworks (MMOFs) have been proven as promising materials for revolutionizing industrial applications, such as storage and separation of gases and purification of NG.1,2 Recently, we reported the synthesis of two novel porous zeolite-like supramolecular assemblies (ZSAs), having zeolite gis and rho topologies, via directional hydrogen-bonding interactions and exhibited permanent microporosity and thermal stability.