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A series of poly (phthalazinone ether sulfone ketone) (PPESK)/multi-walled carbon nanotube (MWCNT) buckypaper nanocomposites with different contents of MWCNT was fabricated by heat press process with alternate laminating of soluble PPESK films and MWCNT buckypapers.Best conditions to infiltrate the resin in the buckypaper were determined by optimizing the residual solvent content in the PPESK film and processing cycle.