DFT Calculations on Mechanism and Enantioselectivity of Pd-Catalyzed Allene Diboration and Chiral Di

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Mechanistic studies utilizing DFT calculations were performed on two reactions involving diborane reagents:Pd-catalyzed diboration of 1,1-disubstituted allenes(Fig.1(a))1 and asymmetric reductive coupling of isoquinolines templated by chiral diborons(Fig.2(a)).
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