芳基功能化的石墨烯的构型决定的电学和磁学性质

来源 :第十三届国际凝聚态理论与计算材料学会议(The 13th International Conference on Con | 被引量 : 0次 | 上传用户:gideonkim
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  芳基功能化的石墨烯体现了构型决定的电学和磁学性质.芳基对吸附在相同(不同)的晶格被被记为M2AA (M2AB)构型.M2AA构型体现了铁磁半导体的特性.自旋向上和向下的子带的禁带宽度分别为1.1和1.2 eV.M2AB构型是非磁性半导体,禁带宽度为0.8 eV.每个芳基可以引入1个玻尔磁子.扶手椅型的纳米带体现了与单层石墨烯相似的磁学性质.石墨烯的磁矩主要分布在石墨烯的边界上.之字形的石墨烯纳米带的M2AA和M2AB构型都可能有净磁矩.每个芳基可以向石墨烯引入1.5-3.5个玻尔磁子.芳基功能化的之字形纳米带体现了金属-绝缘体转变的特性
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