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A M3 modification of tricalcium silicate(C3S)solid solution was investigated using transmission electron microscopy(TEM).Selected area electron diffraction(SAED)patterns and high resolution transmission electron microscopy(HRTEM)images were analyzed based on a pseudohexagonal subcell with cell parameters of a=7.059 (A),b=7.055 (A),c=24.924 (A),α=89.79°,β=90.04° and γ=120.14°.