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In this presentation, I will give several examples of exotic Au nanostructures that we recently fabricated, including (i) a Au-Pd bimetallic nanostructure through site-specific epitaxial growth of Au-Pd alloy horns at the ends of Au nanorods (Figure a);[1] (ii) Chiral Gold Nanowires with Boerdijk-Coxeter-Bernal Structure (Figure b);[2] (iii) 2-D Au nanosheets with a few atomic layer thickness,[3] and (iv) an asymmetric Au nanorod-Au nanoparticle dimer structure (Figure c).