Theoretical Investigations on Asymmetric N-H Insertion of Amines Catalyzed by Palladium-Chiral Guani

• 作 者: Jing Li Junming Wang Zhishan Su Changwei Hu
• 机 构: Key Laboratory of Green Chemistry and Technology,Ministry of Education,College of Chemistry,Sichuan
• 出 处: 第十二届全国物理有机化学学术会议
• 发表日期: 2017年期

　　Asymmetric N-H insertion of amines mediated by Pd(0)-chiral guanidine complex was developed by Feng's group,affording the products with excellent outcomes(up to 99%yield and 94%ee)under mild reaction condition[1].