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By treating a semirigid 5-oxyacetate isophthalic acid(H3OAIP)ligand with MnSO4/CoSO4/CdSO4 under solvothermal conditions,three isostructural cluster organic frameworks,[M2(OH)(OAIP)(DMA)]·H2O(M=Mn2+(1),Co2+(2),Cd2+(3))were constructed.