Preparation of Visible Light-Harvesting Pt(Ⅱ)Complexes Showing Long-lived Triplet Excited States and

来源 :The Asian Pacific Conference on Chemistry of Materials 2015 | 被引量 : 0次 | 上传用户:qinyalin
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Triplet photosensitizers are crucial for photodynamic therapy(PDT),photocatalysis,and triplet-tripletannihilation(TTA) upconversion.[1] Phosphorescent transition metal complexes,such as Ru(bpy)3Cl2(bpy =2,2-bipyridine) were used as triplet photosensitizers.However,the conventional transition metal complexesusually show weak absorption of visible light.For example,the molecular absorption coefficients of Ru(bpy)3at 450 nm is less than 15000 M-1 cm-1.
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