Wtih rapid development of homogeneous gold catalysis,[1] the enantioselective gold catalysis poses considerable challenges,because gold(Ⅰ) complexes strongly prefer to the linear geometry which forces
Due to the prevalence of C(sp2)-P bonds in a wide range of biologically active molecules,pharmaceuticals,phosphine-containing ligands,and functional materials,their formation has attracted considerabl
The asymmetric hydrogenation synthesis of γ-amino alcohols,which are important building blocks of antipressants in clinic medicine such as(S)-Duloxetine,(R)-Fluoxetine,and(R)-Atomoxetine(Figure 1),has
Benzoin esters,which can be easily obtained by benzoin condensation or cross-benzoin reaction,are of interest in fields ranging from useful synthetic intermediates in organic conversions to important
Organocalcium chemistry has developed rapidly in recent years.Its chemistry mainly concentrates on the synthesis,structure determination,and catalytic application of some well-defined calcium complexe
Organocopper(Ⅰ) compounds play an important role in organometallic chemistry and are often proposed as key intermediates in many Cu-promoted or catalyzed organic synthesis.
As part of our continuous efforts to study on the ynamide chemistry,1-2 we recently reported a Zn-catalyzed tandem alkyne oxidation/C-H functionalization for the highly site-selective synthesis of ver
As part of our continuous efforts to study on the ynamide chemistry,we describe herein a novel gold-catalyzed formal [3+2] cycloaddition between ynamides and fully substituted isoxazoles,leading to th