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A new compound,{[Co(bmzbc)2]·2DMF}n (JXNU-1,JXNU denotes Jiangxi Normal University),based on the 4-(benzimidazole-1-yl)benzoate (bmzbc-) ligand has been synthesized and structurally characterized.The Co(Ⅱ) ions are bridged by the rod-like bmzbc- ligands to give a two-dimensional (2D) sheet wherein the Co(Ⅱ) ions are spatially separated from each other by the long bmzbc- rods.