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The dispersion of nano-SiO2 in polyurethane and shape memory (SM) properties of polyurethane nanocomposites were investigated by SEM, DMA and FT-IR dichroism during the stretching process.The results showed that nano-SiO2 dispersed well and enhanced the PU matrix, and t.The shape memory performance of PU-0% was superior to that of PU-3%.