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甲酰胺是一类具有广泛应用的化学品,可以作为工业溶剂与合成其它重要化学品的原料。在还原剂存在下,采用二氧化碳作为碳源是甲酰胺的一条重要合成路线。在本工作中我们发现乙酸铜的2,2-双(二苯基膦基)乙烷(DPPE)配合物可以有效催化胺与CO2的甲酰化反应,并且反应条件温和。
温和条件下铜基催化剂催化的胺与CO2的甲酰化反应
【摘 要】
：
甲酰胺是一类具有广泛应用的化学品,可以作为工业溶剂与合成其它重要化学品的原料。在还原剂存在下,采用二氧化碳作为碳源是甲酰胺的一条重要合成路线。在本工作中我们发现乙酸铜的2,2-双(二苯基膦基)乙烷(DPPE)配合物可以有效催化胺与CO2的甲酰化反应,并且反应条件温和。
【机 构】
：
北京分子科学国家实验室,中国科学院化学研究所分子科学中心,100190,北京
【出 处】
：
中国化学会第30届学术年会
【发表日期】
：
2016年7期
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