Thermal behavior, non-isothermal decomposition reaction kinetics and thermal-safety evaluation on 3-

• 作 者: BiaoYan[1]Hong-YaLi[1]Hai-XiaMa[2]JirongSong[3]FengqiZhao[4]
• 机 构: School of Chemistry and Chemical Engineering,Shaanxi Key Laboratory of Low Metamorphic Coal clean Ut
• 出 处: 中国化学会第四届全国热分析动力学与热动力学学术会议
• 发表日期: 2013年期

　　3-Amino-4-aminoximidofurazan(AAOF)is an important precursor of synthesizing new furazano(furoxano)energetic compound.Its thermal behavior was studied by the differential scanning calorimetry(DSC)method.The results of this study show that there are one melting process and two exothermic decomposition processes.Its kinetic parameters of the intense exothermic decomposition process were obtained from the analysis of the DSC curves.The apparent activation energy,pre-exponential factor and the mechanism function are 146.13 kJmol-1,1010.90 s-1 and f(α)=(1-α)2,respectively.