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Metal organic frameworks show significant promise for the carbon capture and storage (CCS).The effects of pressure and temperature on CCS in Ni/DOBDC metal organic framework were studied experimentally and numerically.The amount and isosteric heat of adsorption at different pressure and temperature were measured.The experimental results show that the Ni/DOBDC has a high CO2 capacity at low temperature of 25 ℃ and moderate pressure at around 100kPa.