【摘 要】
：
以氮化碳材料作为间接催化活性组分[1],利用被其覆盖的负载于氧化铝上的金属镍对其电子性质进行调节,我们设计了一种理念上具有创新意义的耐酸加氢催化剂CN/Ni/Al2O3(图1).该催化剂在酸性条件下表现出了对于硝基类化合物优秀的加氢性能和出色的稳定性,特别是对于强酸条件下硝基苯加氢异构制对氨基酚这种传统上只能采用贵金属作为催化剂的反应(表1)也表现出了优异的性能,且选择性更高.
【机 构】
：
南京大学化学化工学院,南京 210093 新加坡国立大学化学系,新加坡 117543
论文部分内容阅读
以氮化碳材料作为间接催化活性组分[1],利用被其覆盖的负载于氧化铝上的金属镍对其电子性质进行调节,我们设计了一种理念上具有创新意义的耐酸加氢催化剂CN/Ni/Al2O3(图1).该催化剂在酸性条件下表现出了对于硝基类化合物优秀的加氢性能和出色的稳定性,特别是对于强酸条件下硝基苯加氢异构制对氨基酚这种传统上只能采用贵金属作为催化剂的反应(表1)也表现出了优异的性能,且选择性更高.
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