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Complexes of the type R2SnL2, where R =phenyl, butyl and methyl and LH =N-methyl-m nitrobenzohydroxamic acid, have been synthesized and characterized by physico-chemical (elemental analysis, and electrolytic conductance) and spectral (UV-Visible, IR and (1H and 13C and NMR)techniques.Monomer structures for the complexes, bidentate and octahedral geometry was proposed for the complexes prepared.