Synthesis and Crystal Structure of a Bipyridine Bridged Binuclear Copper Complex of Schiff Base Deri

来源 :中国化学会第六届全国结构化学学术会议 | 被引量 : 0次 | 上传用户：candyhaiyu

【摘要】

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【作者】

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Chao-yong Yu Xiao-jun Zhou Yuan-yuan Li Yang Zou

【机构】

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Department of Chemistry,Zhejiang Sci-Tech University,Hangzhou,310018

【出处】

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中国化学会第六届全国结构化学学术会议

【发表日期】

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2012年8期

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　　A novel ternary mixed-ligand complex [Cu2(L)2(bipy)(EtOH)2] (1) (H2L=β-phenylal-anine,N-[1-(2-hydroxyphenyl)propylidene],bipy =4,4-bipyridine,EtOH=ethanol) has been synthesized and characterized by X-ray diffraction.It crystallizes in the monoclinic system,space group P21/c.The Schiff base ligand coordinates to the Cu(Ⅱ) ion in a tridentate mode including phenol-hydroxyl oxygen,carboxyl oxygen and amide nitrogen atom,while the bipyridine ligand coordinates in bidentate bridging mode linking two adjacent Cu(Ⅱ) ions.The binuclear unit are further linked by hydrogen bond to form a 2D wave-like supramolecular architecture.

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Synthesis and Crystal Structure of a Bipyridine Bridged Binuclear Copper Complex of Schiff Base Deri

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