The enamide moiety is a key functionality in numerous natural products and pharmaceuticals with antibiotic,antitumor,cytotoxic,anthelmintic and antifungal activ
Quinoline motifs are widely existed in many pharmacologically compounds.Several medicines contain quinoline scaffold such as quinine(antimalarial),quinidine(ant
Chiral octahedral Ir(Ⅲ) complexes have been widely employed as luminescence probes for nucleic acid[1],enzyme inhibitors[2],as well as asymmetric photoredox ca
6H-Isoindolo[2,1-a]indol-6-ones and indeno[1,2-b]indol-10(5H)-ones,as two important class of indole-containing tetracyclic compounds,have attracted increasing i
Selective sensing of both cationic and anionic species is an interesting topic within supramolecular chemistry.[1] Thiacalix[4]arene scaffolds show unique struc
We previously reported that bromination of osmabenzyne complexes Os(≡CCR=C(Me)CRCH)Cl2(PPh3)2(R = H,TMS) occurs at the metal center as well as the β-carbons t
Ferrocene possesses unique structural and electronic features,and its derivatives popularly serve as an organometallic scaffold extensively used in asymmetric c
The direct conversion of alcohol compounds to α,β-unsaturated nitriles in the presence of acetonitrile is of considerable economic interest since such α,β-u
Palladium species are widely applied in catalysis of versatile organic reactions,drug syntheses,and automobile catalytic converters owing to their excellent cat
[Fe]-hydrogenase can catalyze the activation of H2 in the presence of methenyltetrahydromethanopterin(methenyl-H4MPT+),and its active site contains one Fe atom,