FeCl3促进的[60]富勒烯并四氢喹啉的合成

来源 :第十届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户：sun8888

【摘要】

：

经过近二十多年的发展,许多新的合成策略被应用于新型富勒烯衍生物的合成,为富勒烯化学的发展和应用奠定基础.其中自由基反应尤其是金属盐参与的自由基反应,由于其高效,简捷

【作者】

：

游训王官武

【机构】

：

中国科学技术大学化学与材料科学学院,合肥,230026

【出处】

：

第十届全国物理有机化学学术会议

【发表日期】

：

2013年9期

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经过近二十多年的发展,许多新的合成策略被应用于新型富勒烯衍生物的合成,为富勒烯化学的发展和应用奠定基础.其中自由基反应尤其是金属盐参与的自由基反应,由于其高效,简捷的优势成为这一领域的热点.在此我们研究了2-芳氨基酯(酮)(1a-f)和C60在铁促进下生成[60]富勒烯并四氢喹啉的反应.反应可以在温和的条件下有效地进行,最高产率达到46％,而且对取代基的电子效应的适应性很好.

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FeCl3促进的[60]富勒烯并四氢喹啉的合成

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