论文部分内容阅读
[5.6]-壬烷是萜类化合物中常见的环系结构，特别是带角甲基的 [5.6]-壬烷结构，在许多倍半萜化合物中也发现.这些萜类化合物往往具有重要的生理活性，[1] 长久以来引起合成化学家们的广泛兴趣.
萜类[5.6]-壬烷环系的新颖构建方法研究
【摘 要】
：
[5.6]-壬烷是萜类化合物中常见的环系结构，特别是带角甲基的 [5.6]-壬烷结构，在许多倍半萜化合物中也发现.这些萜类化合物往往具有重要的生理活性，[1] 长久以来引起合成化学家们的广泛兴趣.
【机 构】
：
上海应用技术学院 化学与环境工程学院 上海 201418 中国科学院上海有机化学研究所 天然产物有
【出 处】
：
中国化学会第九届全国有机化学学术会议
【发表日期】
：
2015年7期
其他文献
The amide linkage is a common and very important functional group which contributes to the special properties of peptides,proteins,beta-lactam antibiotics,and numerous synthetic polymers.
会议
苯并噻唑及其衍生物是一类非常重要的杂环化合物,广泛存在于自然界中,在医药、农业及工业[1]等领域有着广泛的应用.过去,主要以邻氨基苯硫酚、N-芳基硫代酰胺或硫脲、邻卤苯胺为原料合成2-取代苯并噻唑[2-3].
会议
三个环共用一个C-C 单键,形似螺旋桨的化合物称为螺旋桨型化合物1,2,它们最早被设计、合成于1965 年3,4.此类化合物有着广泛的应用,很多天然产物中都含有此类结构5,6.
会议
Aryl ketones are important structural motifs in dyes,fragrances,fine chemicals,pharmaceuticals and agrochemicals.
会议
Effective Chirality Transfer in [3+2] Reaction between Allenyl-Rhodium and Enal:Mechanistic Study Ba
conclusion 1.The newly DFT method,MII-L,was used to explore the mechanism of this intramolecular [3+2]cycloaddition reaction,which gives[3.3.0]bicyclic ring systems with two vicinal quaternatry carbon
会议
Diruthenium Complexes with Bridging Diethynyl Polyaromatic Ligands:Synthesis,Spectroelectrochemistry
It has been well documented that diruthenium complexes linked through a common π-system,allow for a facile intramolecular electron transfer.
会议
Gold(Ⅰ)-catalyzed regiodivergent intramolecular hydroarylation of carbon-carbon triple bond was established,tuned by electronic and steric property of ligands coordinated to gold(Ⅰ) center.
会议
Mechanism,Chemoselectivityand Enantioselectivityfor Rhodium-Catalyzed DesymmetricSynthesis of Hydrob
Rhodium-catalyzed desymmetrization of cyclohexadienones is an efficient method for the asymmetric synthesis of hydrobenzofurans.The newly reported density Functional theory(DFT)method MN 12-L is used
会议
The Mechanism of N-O Bond Cleavage in Rhodium-Catalyzed C-H Bond Functionalization of Quinoline N-ox
The mechanism and regioselectivity of the [RhⅢCl2Cp*]2-catalyzed C-H bond functionalization and N-O bond cleavage of quinoline N-oxide with alkynes were studied by using DFT calculations,which suggest
会议
Pd(O)-Catalyzed Cross Coupling of Allyl Halides with N-Mesylhydrazones:Synthesis of1,3-Diene Compoun
Conjugated 1.3-dienes are considered as basic frameworks in natural products and functional materials.
会议