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亚甲胺叶立德与不饱和烃的不对称1,3-偶极环加成反应,由于高效性、原子经济性和易于控制选择性等优势,已经发展成为合成多取代手性吡咯烷的重要方法1.此外,作为氨基酸的基本单元,亚甲胺叶立德参与的不对称Michael 反应也被广泛应用于构建各类非天然α-氨基酸衍生物.
基于亚甲胺叶立德的不对称催化反应
【摘 要】
：
亚甲胺叶立德与不饱和烃的不对称1,3-偶极环加成反应,由于高效性、原子经济性和易于控制选择性等优势,已经发展成为合成多取代手性吡咯烷的重要方法1.此外,作为氨基酸的
【机 构】
：
华东理工大学药学院上海200237
【出 处】
：
中国化学会全国第十二届有机合成化学学术研讨会
【发表日期】
：
2015年10期
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