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在已有的研究基础上,综述了近年来金属配位化合物溶液的电化学研究.内容包括:采用多种电化学方法研究金属配合物、簇状化合物溶液的电化学,配合物氧化还原电对的标准电极电位及有关的平衡常数,配合物的电极反应动力学及其与结构性能的关系,配合物的电催化作用,配合物的电合成.探讨配合物电极反应机理,测定多种电化学参数,提供了许多关于配合物性质、结构和功能的重要信息
Based on the existing studies, the electrochemical studies of metal coordination compounds in recent years are reviewed. The contents include: Electrochemistry of metal complex, cluster compound solution, standard electrode potentials of complex redox couples and related equilibrium constants, the electrode reaction kinetics of complex and its structural properties The electrocatalysis of complexes, the electrosynthesis of complexes. Explore the complex electrode reaction mechanism, the determination of a variety of electrochemical parameters, provides a lot of important information on the nature, structure and function of the complex