含有机硅烷席夫碱配体的金属钌化合物

来源 :第七届全国物理无机化学会议 | 被引量 : 0次 | 上传用户：SleepOrWake

【摘要】

：

利用系列硅烷偶联剂试剂一端的硅烷氧基团和含有硅羟基的介孔材料缩合反应,生成与-Si-O-Si-C-等类似的稳定化学键基团而形成负载连接,将另一端含有-NH2、-PPh2 等可反应成键的配位基团与金属钌化合物反应,合成出结构确定的以金属钌为中心的异相催化剂前驱体[1],我们用浸渍法把有机硅钌化合物负载到介孔分子筛SBA-15 上得到可调的固载异相金属钌催化剂.

【作者】

：

施立苗吴福乐贾爱铨张千峰

【机构】

：

安徽工业大学,分子工程与应用化学研究所;安徽省马鞍山市湖东路59号,243002

【出处】

：

第七届全国物理无机化学会议

【发表日期】

：

2016年7期

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含有机硅烷席夫碱配体的金属钌化合物

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