Sequential Formation of Ruthenoles via 1,3-Yonoe Capped Tetraruthenium Cluster

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户：hezhimou

【摘要】

：

　　The carbonyl donor of an alkyne capping ligand stabilizes a reactive tetraruthenium framework,which sheds light on the fragmentation and formation of low-va

【作者】

：

JindouYang;ZiweiGao;WeiqiangZhang;GuofangZhang;

【机构】

：

Key Laboratory of Applied Surface and Colloid Chemistry,MOE/School of Chemistry and Chemical Enginee

【出处】

：

第九届全国无机化学学术会议

【发表日期】

：

2015年期

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　　The carbonyl donor of an alkyne capping ligand stabilizes a reactive tetraruthenium framework,which sheds light on the fragmentation and formation of low-valence ruthenium clusters.The thermolysis reaction of the triruthenium cluster,Ru3(CO)12(1)with 1,3-ynone,1-(4-methoxyphenyl)-3-phenylprop-2-yn-1-one(2)were systematically investigated.

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Sequential Formation of Ruthenoles via 1,3-Yonoe Capped Tetraruthenium Cluster

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