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Mn1.5Co1Ni0.5O4(MCNO)thin films were deposited on different materials by Chemical Solution Deposition(CSD)Method,and then CBP was spun-coated on MCNO thin film.The study shows that Mn1.5Co1Ni0.5O4 thin film deposited on Mn1.5Co1Ni0.35Cu0.15O4(MCNCuO)or Mn1.5Co1Ni0.2Cu0.15Sc0.15O4(MCNCuScO)thin film facilitates the electrical conductivity of MCNO/CBP multilayer.The energy gap between Fermi level of Mn1.5Co1Ni0.5O4 thin film and HOMO level of CBP film in MCNCuO/MCNO/CBP multilayer is smaller than the one in MCNCuScO/MCNO/CBP multilayer.The energy gap between the Fermi level of Mn1.5Co1Ni0.5O4 thin film and the HOMO level of CBP film in MnCo2O4/MONO/CBP multilayer is smaller than the one in NiMn2O4/MCNO/CBP multilayer.