【摘 要】
：
A novel 3,3-(anthracene-9,10-diyl)dipentane-2,4-dione-bridged di-vanadium(IV) complex,[(VO)2(C24H20O4)(C15H11O2)2] (C15H11O2=1,3-diphenylpropane-1,3-dione anion; C24H20O4=3,3-(anthracene-9,10-diyl)dip
【机 构】
：
宜春学院 江西省高校应用化学与化学生物学重点实验室,江西宜春 336000 宜春学院 江西省高校应
【出 处】
：
中国化学会第十六届全国化学热力学和热分析学术会议
论文部分内容阅读
A novel 3,3-(anthracene-9,10-diyl)dipentane-2,4-dione-bridged di-vanadium(IV) complex,[(VO)2(C24H20O4)(C15H11O2)2] (C15H11O2=1,3-diphenylpropane-1,3-dione anion; C24H20O4=3,3-(anthracene-9,10-diyl)dipentane-2,4-dione dianion),was synthesized and characterized by the element analysis,conductivity,infrared spectra,electronic spectra and ESI-MS.Thermogravimetry(TG) and differential scanning calorimetry(DSC) for compound in an atmosphere of N2 was performed.From 155~197℃,197~311℃,311~516℃,a mass loss 0f 16.95%,15.78% and 33.94% are observed,respectively.The max peaks at 179℃,268℃ and 465℃ in DTG are observed by exothermic decomposed reaction,respectively.
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