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Gas processing operations conducted at high velocities (e.g., filtration and catalytic reaction) require specialized media and structure in order to achieve the highest possible level of filtration and/or reaction per unit of pressure drop.A novle catalyst structure, microfibrous entrapped catalyst (MFEC) have potential to achieve high conversion with negligible pressure drop in cases requiring high mass flow rates, compared to other media, e.g., wash-coated monoliths and catalyst particultes in packed bed reactors.