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this article is the research on value order of the syndrome elements based on differentiation diagnosis during the clinical practice of inquiry of Traditional Chinese Medicine.In order to fit the principle of Chinese diagnostics, a complex system model of Traditional Chinese Medicine diagnosis has been conducted by applying the description of multilayer complex system, and there are three layers of complex system model included diseases, syndromes and symptoms.After establishing the framework of diagnosis knowledge of Traditional Chinese Medicine by using the mathematics method of formal concept analysis;a new diagnosis method of Traditional Chinese Medicine has been proposed based on representation principle of structural partial-ordered attribute diagram, intend to fulfill the request of clinical application.This method provided a scientific solution for analyzing the syndrome element value order of Chinese diagnostics by merging multi-disciplines.During the clinical application, there are total 112 cases has been collected.Among this eases, there are 48.21 percent of it has over 80 percent matches with the diagnosis of clinical experts, and there are 90.18 percent of it has over 60 percent matches with the diagnosis of clinical experts.The result of this method corresponded the Chinese diagnostics, and its effectiveness and practicability has been proved.