The Origin of the High Regioselective Copper-Catalyzed Benzylic C-H Amination by N-Fluorobenzenesulf

来源 :International Conference on Theoretical and High Performance | 被引量 : 0次 | 上传用户：woaifulei

【摘要】

：

【作者】

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Jingping Zhang Yiying Zheng Qian Zhang

【机构】

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Faculty of Chemistry, Northeast Normal University, Changchun 130024, China

【出处】

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International Conference on Theoretical and High Performance

【发表日期】

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2013年4期

【关键词】

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Copper-catalyzed benzylic C-H amination single-electron transfer

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　　Transition-metal-catalyzed C-H bond functionalizations are of great synthetic and theoretical values.1 Direct C(sp3)-H animation has led to significant results since the discovery of metal nitrenoids, but highly free nitrene is with low selectivity.Therefore, the development of regioselective direct C(sp3)-H animation is highly desirable.

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The Origin of the High Regioselective Copper-Catalyzed Benzylic C-H Amination by N-Fluorobenzenesulf

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