Synthesis and Characterization of Branched Sulfonated Poly (Biphenylene-co-Sulfone) Ether Membranes

来源 :The 6th International Conference on Separation and Technolog | 被引量 : 0次 | 上传用户:flyfox521
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  Proton exchange membrane fuel cells (PEMFCs) have attracted considerable attention as new power sources for vehicles and portable devices.Currently,Perfluorosulfonic acid membranes such as Nation(@) are the current state-of-the-art PEM materials because of their superior chemical and electrochemical stability,high proton conductivity.However,perfluorosulfonic acid membranes have critical drawbacks:high preparation cost,high methanol crossover,poor mechanical stability at devated temperatures(T > 80℃).Hydrocarbon based polymers have been investigated to recover these drawbacks.The other potential materials are partially fluorinated polymers,which are expected to have the advantages between perfluoropolymers and hydrocarbon based polymes.
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