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The phase separation of glasses of the 17(CaO+MgO)-6Na2O-6AhO3-65SiO2-x(B2O3 +P2O5)(0 ≤ x ≤6) (wt%) series were investigated using DSC, XRD and SEM.The X-ray diffraction (XRD) and differential scanning calorimetry (DSC) showed that there were two amorphous phases in the glasses.