Determination of 1-hydroxypyrene in airborne particulates by a high sensitive chemiluminescence comb

• 作 者: RuiboLi[1]TakayukiKamed[2]YingLi[3]AkiraTorib[2]NingTang[3]KazuichiHayakaw[2]Jin-MingLin[4]
• 机 构: School of Science, Beijing University of Chemical Technology, Beijing 10029, China
• 出 处: 第2届大连国际色谱学术报告会、第37届国际高效液相色谱及相关技术会议、第18届全国色谱学术报告会
• 发表日期: 2011年期

　　Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants that are generated from incomplete combustion of organic matters such as fuel oil and coal.In the atmosphere, PAHs react with the co-pollutants, such as ozone and nitrogen oxides (NOx) to produce substituted PAHs.One type of substituted PAHs is hydroxylated PAHs (OH-PAHs).They may be generated from photochemical reactions of PAHs or combustion of coal.OH-PAHs have endocrine disrupting activities such as estrogenic activities or antiestrogenic activities.Atmospheric concentrations of OH-PAHs were reported to be in the pg/m3 range, which are 1-3 orders of magnitude lower than that of PAHs.Therefore, it is necessary to establish a highly sensitive and reliable method for determination of OH-PAHs in atmosphere.