Block copolymeriztion of propylene and epoxides by titanium-aluminum dual catalyst system

来源 :Asian Polyolefin Workshop (APO2013)2013亚洲聚烯烃研讨会 | 被引量 : 0次 | 上传用户：fighterok

【摘要】

：

Previously we reported block copolymerization of norbornene, propylene and methyl methacrylate (MMA) using fluorenylamidotitanium complex (1) activated by a mix

【作者】

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Ryo Tanaka Yuushou Nakayama Takeshi Shiono

【机构】

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DepartmentofAppliedChemistry,GraduateSchoolofEngineering,HiroshimaUniversity,1-4-1Kagamiyama,Higashi

【出处】

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Asian Polyolefin Workshop (APO2013)2013亚洲聚烯烃研讨会

【发表日期】

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2013年10期

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Previously we reported block copolymerization of norbornene, propylene and methyl methacrylate (MMA) using fluorenylamidotitanium complex (1) activated by a mixture of MMAO and 2,6-di-tert-butyl4-methylphenol (BHT) as a catalyst.In this polymerization, the former olefin polymerization proceeds with cooridination-insertion mechanism and the latter MMA polymerization takes place with anionic mechanism, which is initiated by the nucleophilic attack of metal enolate to the carbonyl group activated by aluminum Lewis acid.

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Block copolymeriztion of propylene and epoxides by titanium-aluminum dual catalyst system

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