High-Temperature Spin Crossover in Two Solvent-Free Coordination Polymers with Unusual High Thermal

• 作 者: Wei Liu Zhao-Ping Ni Ming-Liang Tong
• 机 构: Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education,School of Chemistry
• 出 处: 中国化学会第八届全国配位化学会议
• 发表日期: 2017年10期
• 关键词: Spin Crossover iron(Ⅱ) Coordination Polymers Structural-Magneto Relationship

　　Two solvent-free two-dimensional(2D)coordination polymers,2∞[Fe(ptim)2](1)and 2∞[Fe(ptpy)2](2)(Hptim = 2-(5-(4-(1H-imidazol-l-yl)phenyl)-4H-1,2,4-triazol-3-yl)pyridine; Hptpy = 2-(5-(4-(pyridin-3-yl)phenyl)-4H-1,2,4-triazol-3-yl)pyridine),have been successfully prepared by solvothermal reactions.