手性的膦烷-咪唑啉PCN钳形钯化合物的合成与表征

来源 :第十八届全国金属有机化学学术讨论会 | 被引量 : 0次 | 上传用户：yin329060357

【摘要】

：

钳形钯化合物已被证明是催化Suzuki、Heck、Sonogashira、Aldol、Michael加成等多种类型反应的有效催化剂[1].特别是近年来的研究发现,一些手性的钳形钯化合物在不对称催化反应中也能表现出高度的立体选择性,例如:使用含有手性苄基的双(膦烷)PCP钳形钯化合物作为催化剂,烯酮、硝基烯烃等缺电子烯烃的膦氢化反应均获得了优异的对映体选择性[2].

【作者】

：

杨晶晶原立华龚军芳宋毛平

【机构】

：

郑州大学化学与分子工程学院,河南省化学生物与有机化学重点实验室,郑州450001

【出处】

：

第十八届全国金属有机化学学术讨论会

【发表日期】

：

2014年5期

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