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Recently,conductive carbonaceous nanoparticles/polymer nanocomposites(CNPN)has received great attention because of their oustanding electrical properties.According to the percolation theory,the conductive polymer composites will show a insulator-to-conductor transition when the filler concentration reaches its electrical percolation threshold,which is the minimum filler concentration to build up conductive percolated pathway through the polymer matrix.It is known that the electrical percolation threshold not only depends on the conductivity of the fillers,but also depends on the dispersion and morphology of the fillers in the polymer matrix.Therefore,it will be an efficient strategy to improve the electrical properties of CNPN by controlling their microstructures and morphologies.