Direct Measurement of T-P-dependent Reaction Kinetics and Branching of Vinyl radical+Acetylene

• 作 者: GuozhuLiu[1]ZacharyJ.Buras[2]WilliamH.Green[3]
• 机 构: Department of Chemical Engineering,Massachusetts Institute of Technology,Cambridge,Massachusetts,Uni
• 出 处: 中国化学会第30届学术年会
• 发表日期: 2016年期

　　Vinyl(C2H3)+acetylene(ethyne,C2H2),one of the important building block reactions to form aromatic rings,was studied using laser flash photolysis-laser absorbance spectrometry and time-resolved photoionization time-of-flight mass spectrometry(LFP-LAS-PI TOF MS)from 300-700 K and 5-50 Torr.