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本文设计合成了二氨基马莱腈和具有不同取代基的水杨醛的三种不对称席夫碱配体,幵合成了它们的锌(Ⅱ)不镁(Ⅱ)的配合物,在引入不同富电子基团和缺电子基团后由于取代基的推/拉电子性,使得体系化合物具有良好的荧光性质[1,2]。
不对称二氨基马莱腈席夫碱配合物的荧光调控
【摘 要】
：
本文设计合成了二氨基马莱腈和具有不同取代基的水杨醛的三种不对称席夫碱配体,幵合成了它们的锌(Ⅱ)不镁(Ⅱ)的配合物,在引入不同富电子基团和缺电子基团后由于取代基的推/拉电子性,使得体系化合物具有良好的荧光性质[1,2]。
【机 构】
：
北京理工大学,化学学院,原子分子簇科学教育部重点实验室,北京,100081
【出 处】
：
中国化学会第八届全国配位化学会议
【发表日期】
：
2017年10期
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