NHC-Based Organometallic Polymers as Atomically Dispersed SolidCatalysts toward Biomass Transformati

来源 :中国化学会第十三届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户:apenggejiayou
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  A series of robust atomically dispersed solid molecular catalysts based on privileged NHC-metal complexes werereadily fabricated via self-assembly from diverse bis-benzimidazolium salts with selected metal precursors.Among them,the NHC-Ru and NHC-Ir polymers have demonstrated high catalytic activity and excellent stabilityas atomically dispersed solid catalysts in hydrogenation,dehydrogenation,and reductive amination reactionsinvolving a number of biomass platform molecules at very low catalyst loadings.
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