A unique 3-D chiral Zn(Ⅱ) coordination framework with 1,2,3-benzenetricarboxyl and 4,4'-bipyrid

• 作 者: Lu-Fang Ma Qian-Hua Qin Li-Ya Wang
• 机 构: College of Chemistry and Chemical Engineering, Luoyang Normal University,Luoyang,471022,P.R.China
• 出 处: 中国化学会第八届全国无机化学学术会议
• 发表日期: 2011年9期

Hydrothermal reaction of Zn(Ⅱ) acetate,4,4-bipyridyl (bpy) and 1,2,3-benzenetricarboxylic acid (H3bta) results in a 3-D coordination framework {[Zn4(bta)2(Hbta)(bpy)3](H2O)3}n (1),which shows the self-penetrating net with a new 4-connected topological prototype and chiral helical character.