D2分子光解D2+XUV→D(2s,2p)+D(1s)D(2s)和D(2p)通道的量子干涉

来源 :第十五届全国化学动力学会议 | 被引量 : 0次 | 上传用户:jerryhua1987
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氢气分子的光解是电子结构理论计算和光解动力学理论的试金石.对于标题中的D2解离动力学,1987年的文献预测:生成D(2s)和D(2p)产物的分支比在解离阈值(14.76 eV)附近随产物平动能的变化发生振荡.[1] 我们在实验中第一次观测到了这个现象.
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