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Since the shortage of the traditional fossil fuel and CO2 emission issues,[1-2] it become a political and technological priority to develop the renewable and clean energy sources.Here,we developed series of covalent organic polymers(COPs)[3] constructed from covalent bonds(B-O,C-C,C-H,C-N et al.)between the ever-changing organic linkers by homo-or hetero-polymerization,a similar category as MOFs,[4-5] for energy storage and conversion.Using COP pre-cursors,we have developed a new strategy for location control of N-dopant heteroatoms in the graphitic porous carbon,which otherwise is impossible to achieve with conventional N-doping techniques.The electrocatalytic activities of the N-doped holey graphene analogues are well correlated to the N-locations,showing possibility for tailoring the structure and property of N-doped carbon nanomaterials.[6] Furthermore,by incorporating non-precious metals(such as Fe,Co,Mn),the newly developed metal-incorporated C-COP materials were found to show efficient electrocatalytic activities toward 4e oxygen reduction in both alkaline and acid media with an excellent stability and free from any methanol-crossover/CO-poisoning effects(Fig.1).[7] Clearly,therefore,these newly-developed COP materials hold great potential as efficient ORR catalysts for fuel cells.