高价碘试剂参与的反应方法学研究

来源 :中国化学会第29届学术年会 | 被引量 : 0次 | 上传用户：zhdj600

【摘要】

：

芳基高价碘盐,Ar2I+X-是一类简单易得、环境友好的亲电性有机合成试剂。目前的研究中,芳基高价碘盐与众多亲电试剂反应主要提供芳基正离子得到芳基化产物。我们课题组利用芳基高价碘为原料,发现了一种合成邻位二取代苯环的新方法。利用高价碘试剂诱导的亲电环化反应,报道了三组份反应合成喹啉、喹唑啉等重要含氮杂环的新型合成方法。

【作者】

：

陈超陈俊杰彭静

【机构】

：

清华大学化学系,北京,100084

【出处】

：

中国化学会第29届学术年会

【发表日期】

：

2014年1期

【关键词】

：

高价碘苯环杂环喹啉

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