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In the conversion of biomass-derived synthesis-gas into clean fuels (BTL), one-step synthesis of liquid-range hydrocarbons(C5-C20) is favorable, because of the need of small-scale facility.We found not only Ru-Mn/g-Al2O3 catalyst, but also Ru-Mn/tube system suitable for this purpose.Also, we found novel Ru/modified SiO2 catalyst, which was comparable to that of Ru-Mn-Al2O3 under FT conditions.