【摘 要】
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In recent publication [1]we have reported that α-methylstyrene is polymerization and nitration with nitric acid by one-pot method,polymer with high degree of nitration was obtained.But the steric stru
【机 构】
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School of Biology and Chemical Engineering,Jiangsu University of science and technology
【出 处】
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The 6th International Symposium on Polymer Chemistry(2014年第六
论文部分内容阅读
In recent publication [1]we have reported that α-methylstyrene is polymerization and nitration with nitric acid by one-pot method,polymer with high degree of nitration was obtained.But the steric structure of product was not discussed,Cationic polymerization of α-methylstyrene yields a mostly syndiotactic polymer,which,however,does not crystallize even when the syndiotactic content is highter than 90 ％[2].
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